Update inbound!
Here is the current set-up as tested, missing the external panels, power button and in need of some cable tiding but pretty much there. The syringe was used to fill the loop so I stuck it in the picture too.
A 330ml can and the power prick to give a reminder of size (or lack of it!).
The external dimensions turned out to be:
Length: 246mm
Height: 214mm
Width: 91mm
Total volume (excluding a 330W dell power brick) is 4.79L, so I have gone a little over my target but I'm pretty happy with the volume.
Lots of people are interested in temperatures. I did a ~30 min Furmark and Prime 95 (small FTT) run, then took temperature readings with a non-contact thermometer.
Room temperature: 17.3°C (I do all my work in the garage)
Then starting at the fans: 21.3°C
The radiator on the inlet side: 37.0°C (Toasty)
The radiator on the outlet side: 31.6°C (much better)
The SSD: 40.0°C
Chipset: 45.2°C
Screenshot of system temps / settings all after 30 minutes of FurMark and Prime 95 run simultaneously (temps seemed to have stabilised and then dropped down slightly...?):
CPU: 50-52°C, Max of 57°C
GPU: 37°C, Max of 40°C
Pump ~2600RPM
Fans ~2000RPM
Given the temperatures are so low, with a bit of tinkering I should be able to dial the fans back and maybe scale the pump back a bit too.
Success!!!