I would be wary of using a thermosoftening plastic for something intended to carry high currents. But what would probably work well would be to take an existing (incorrectly keyed) connector, remove the pins to leave only the plastic part, carefully file the lower-centre pin to have the correct notches (could be done by cutting that peg off, filing it, then reattaching it), then use it as a master to create a two-part mould. That mould can then be used to cast a thermoset plastic suitable for use as a connector. The only remaining issue would be sourcing the pins themselves.