Add2psu syncs 2 or more atx psus. The idea is one main psu powers the motherboard, while others power gpus. I said gpus because these started off at cryptomining scene where you'll have like 6 gpus plugged into x1 to x16 powered usb riser. Norm motherboard won't be able to power this many gpus, so each gpus are powered separately. This way you can use 2 or 3 500W psus, split the loads between them.
Now you can just jump these psus and have them powered all the time, but it means if your mobo is turned off your other separately powered gpus will still be on.
Using add2psu gives a cleaner solution where ps_on signal is replicated throughout so that these gpus turn on and off according to the mobo.